However, the safety mark requirements for large means of containment with a capacity of greater than 450 L but less than or equal to 3000 L (i.e., an intermediate bulk container) are: Placards are not required for overpacks as the definition and description for an overpack does not include large means of containment. TDG "Special Case and Special Provision Exemptions, NITROSTARCH, WETTED with not less than 20% water, by mass, ADSORBED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. Large means of containment: These words must be displayed on two opposite sides of the large means of containment in addition to any other safety marks that are required under the TDG Regulations. Dangerous goods are classified into 9 classes, based on the substances characteristics and properties. Column 5 Packing Group Contains the packing group number (i.e. stream The type of packages must be indicated by description of the package (for example, 12 drums). It is used for dangerous goods that do not have a specific entry by name in Schedule 1. Browse our full range of workplace health and safety products and services. The primary class is the class of dangerous goods that takes precedence over any other class. Which one is the correct one? Miscellaneous Class 1 - Explosives Flash point: Primary and Subsidiary Classes entries are assigned with special provisions 274 or 318 (see column 6 in the example below). If the dangerous goods are biohazardous substances (Class 6.2), the consignor may use the classification determined by Health Canada or the Canadian Food Inspection Agency. (7) The number and type of packages must be indicated. Dangerous goods that can be shipped under this exemption will have a limited quantity index greater than 0 in Column 6(a) of Schedule 1 of the TDG Regulations. "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#b{ogw~0B"ty'{~Oi"v?`"DqXmImPiww#R{;?j}J3]0{ ?>]|YlbE#SsBsz/E":}NCg7ON2P5N}s/w?9LO?zZ^/1BWu~N"r~!P;1FAS*:hzQHo _+3l3E6FAsmH}]fwcxoCcbb,!7cTvt{o&h: foC"uF2c;&4m;vx?=8 ga ` !%6M`Wn-@lM;#={CSaW+r:&|gB7/ndJlXqFxs1}n]N:=jd#]5$b{9NF">OL_7!y;3~*cQlCek4o6 eeGn:9P_mO}W'^q7{X,V{TFi8Qj eg/od{QVg{*Ky3n_0ht vv@9g;OkRz~w}79!^C:[7C .{;T/tUOB9x|]\;Q7W{!~uhM Note: This document is a general overview of the TDG classification requirements. Code 3701:1-50-23 - 3701:1-50-23 - Advance notification of shipment of irradiated reactor fuel and nuclear waste. There may be occasions when several different shipping names can be used. Assigning a substance into a hazard class is usually done by the consignor. Classification is normally done by (or in consultation with): If you are the manufacturer of the product, the product must be tested according to Part 2 of TDG Regulations. That legal outcome opened the door to hire a new design and construction team to finish the North Course. b) The laboratory test results show the product falls into one class and one packing group. (6) For transportation by aircraft, the total net mass per package, must be shown unless a gross mass is indicated in Columns (9A) or (9B) of the 172.101 table in which case the total gross mass per package must be shown; or, for Class 7 materials, the quantity of radioactive material must be shown by activity. This mark is required when shipments meet the limited quantity exemption, and must be displayed on one side of a means of containment. Subscribe to Free Newsletter subsidiary class Scheduled maintenance - Thursday, July 12 at 5:00 PM Column 4 Subsidiary Risk(s) Contains the class number(s) of any subsidiary risk(s). Mercury Mercury is a naturally occurring trace metalloid element and known neurotoxin with atomic symbol Hg, atomic number 80, and atomic weight 200.59. Elevated temperature liquid, n.o.s., at or above 100C (212F) and below its flashpoint including molten metals, molten salts, etc. (ii) The hazard class need not be included for the entry Combustible liquid, n.o.s.. means Not Otherwise Specified. Ohio Admin. Example: UN 1263, PAINT (triethylbenzene), Class 3 PG III (27 celcius degrees c.c. : AC413650000; AC413650025; AC413650050; AC413651000; AC413655000 CAS No 7783-35-9 Synonyms Mercuric sulfate The term "MARINE POLLUTANT" shall be put in the end of dangerous goods descriptions. Generally, the shipping name should be selected in the following hierarchical order: 1. Are safety marks required on consolidation bins? WebThere are 9 main classes of dangerous goods. Although a consignor may also use the classification of the manufacturer or a previous consignor, the consignor is still responsible for making sure the classification is correct, and for making a proof of classification available to the Minister. For transport from the United States into Canada by road vehicle or railway vehicle, the shipping name used must be one that is recognized in Schedule 1 of the TDG Regulations or in the UN Recommendations. WebSubsidiary Hazard Class6.1 Packing Group III IMDG/IMO UN-No UN2809 Proper Shipping Name Mercury Hazard Class 8 Subsidiary Hazard Class6.1 Packing Group III 15. For example: UN 1993, Flammable liquids, n.o.s. UN-2 In addition to the above toggle, you may choose to provide the information requested in this opt-out form, which may enable us to take action on your opt-out It is determined according to the specification in section 2.8 and the Precedence of Classes Table which is provided in Part 2. Once the material has been tested at a laboratory, the test results are compared to the classification criteria in Part 2. http://www.unece.org/fileadmin/DAM/trans/danger/publi/unrec/rev16/English/02E_Part2.pdf. How do I determine the identification number / UN Number? Read More: Marine Pollutants & Environmentally Hazardous Substances: Definition, Marking and Exceptions. If the product's name (e.g., chemical name) is listed in Schedule 1 or 3 then the primary hazard class is in Column 3 of Schedule 1 and in Column 2 of Schedule 3 for that shipping name. Inhalation Hazard words for Class 6.1 and Class 2.3 dangerous goods, Category B Mark for UN3373 dangerous goods, Package certification marks (if required), Placard for the primary hazard class on each side and each end (total of four) for each dangerous good. You can If you have questions or need any help, please contact our sponsor. For example, if you have a product for which you determined that the shipping name will be FLAMMABLE LIQUID, N.O.S. sponsor this page to leave your contact info on this page.. Which technical names shall be given in parenthesis for generic entries and N.O.S entries? Determine the other classification elements (i.e., hazard class, packing group, etc.). Meanwhile the actual assigned category is obtained from Appendix 3 in Part 2. For more details, consult the legislation directly. The classification or shipping description is reported in the following order as per Part 3.5: (ii) the shipping name and, immediately after the shipping name unless it is already part of it, (a) for dangerous goods that are subject to special provision 16, the technical name, in parentheses, of at least one of the most dangerous substances that predominantly contributes to the hazard or hazards posed by the dangerous goods, and. Yes. For example, based on the above information from Schedule 1 we have the following information for UN1203: Schedules 1 and 3 will also indicate if any shipping routes are forbidden. For example, both gasoline and diesel are listed by their name in Schedule 1. Regs. The subsidiary hazard class or division number is not required to be entered when a corresponding subsidiary hazard label is not required. WebClassification of dangerous goods is broken down into nine classes according to the type of danger materials or items present, click on a class to read more details; 1. Example: UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. How do I report the classification or shipping description on a shipping document? Mercury and its compounds. Flammable Gases 3. What safety marks are required on a large means of containment (capacity 450L or more)? >> Mercury is a highly toxic metal and can cause skin irritation, skin rashes, allergic reactions. the other class that further identifies the hazards of the dangerous goods. The labelling requirements for an overpack depend on whether the labels can be seen through the overpack. Setup. Figure 4: Placard requirements and placement for compartmentalized means of containment. For detailed information, please see Part 2 of TDG Regulations. If the dangerous good is an explosive or radioactive material, it must be classified as required by other regulatory authorities. For goods having multiple risks which are not specifically mentioned by name in Dangerous Goods List, you have to follow the following hazard precedence rules to determine their primary hazard class and subsidiary class. 120.790 - 120.790 - Advance Notification of Shipment of Nuclear Waste, 180 Neb. 1273 0 obj <> endobj WebIf a type 3 vessel carrying Class 1 DG on board would staying over-night at the WDGA, notification in writing to the Dangerous Goods Unit of the Marine Department will need to be given. 49 CFR 172.202 - LII / Legal Information Institute what is subsidiary class for mercury - Fashion Inspiration and 157.94 - DHS 157.94 - Operating controls and procedures. Shipping Limited Quantities or Excepted Quantities from Guide for Preparing SHIPPING PAPERS - Transportation 1289 0 obj <>/Filter/FlateDecode/ID[]/Index[1273 31]/Info 1272 0 R/Length 79/Prev 99077/Root 1274 0 R/Size 1304/Type/XRef/W[1 2 1]>>stream The rules are set out in a table, the segregation table in 7.2.4, and also have to be applied in respect of any subsidiary class. The technical name shall be a recognized chemical or biological name, or other name currently used in scientific journals and handbooks. Figure 3: Labels on cylinders. NOTE: The size of the Inhalation hazard letters vary for different types of means of containment. Self-heating solid, toxic, organic, n.o.s. For example, UN2744, Cyclobutyl chloroformate, 6.1, (8, 3), PG II. Shipping descriptions for hazardous materials offered or intended for transportation by rail that contain all the information required in this subpart and that are formatted and ordered in accordance with recognized electronic data interchange standards and, to the extent possible, in the order and manner required by this subpart are deemed to comply with this paragraph. Explosives 2. Has a subsidiary classification of Class 1 (1.1,1.2, 1.3 above the exemption limits), Class 4.3, Class 6.1 (Packing Group I), Class 8 (applies only to UN numbers N2977 and UN2978). Subscribe to Free Newsletter Regulations) for the transportation of dangerous goods by road. See Section 2.5. Other requirements may be listed in other sections, regulations, Codes, or Acts that are not listed in this table. We expect this update to take about an hour. Access to this website Note: The information below is provided as guidance only. ); a person who formulates, blends or otherwise prepares mixtures or solutions of goods (e.g., chemist); or. ?O.Q\tF,"V4Iuu8jhb7ew?NI ~eS^lsEU_{\3>e; F]u:MvF7Bz3Jz;O>tzw5qy:!&|]&$fG6F`B@a'\` Eno14}tQ`?K4%1nFh,D_Qg4f>~j $7NH s:o~P;v4fRd%r{6|;>v&K >Z!O~X}u!wv=@~0}$vN=. Transportation of Dangerous Goods (TDG) - 9 Classes, TDG "Special Case and Special Provision Exemptions. a person capable of understanding the nature of the dangerous good (e.g., manufacturer's professional employees such as a chemical engineer, chemist, scientist, etc. For example, UN3518 ADSORBED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. has three hazard classes assigned to it in Column 3 of Schedule 1. Solutions or Mixtures: When a solution or a mixture consists of one dangerous good mixed with non-dangerous goods (e.g., water) and the properties for the solution are the same as for the pure substance, the shipping name is followed by the word solution or mixture as applicable. WebProduct Name Mercury(II) sulfate Cat No. For example: Which labels or placard that must be displayed depend on the classification of the dangerous good. Where the kits contain only liquids, or solids and liquids, the net mass of liquids within the kits is to be calculated on a 1 to 1 basis, i.e., 1 L (0.3 gallons) equals 1 kg (2.2 pounds); (iii) For dangerous goods in machinery or apparatus, the individual total quantities or an estimate of the individual total quantities of dangerous goods in solid, liquid or gaseous state, contained in the article must be shown; (iv) For dangerous goods transported in a salvage packaging, an estimate of the quantity of dangerous goods per package must be shown; (v) For cylinders, total quantity may be indicated by the number of cylinders, for example, 10 cylinders;, (vi) For items where No Limit is shown in Column (9A) or (9B) of the 172.101 table, the quantity shown must be the net mass or volume of the material. Code 246-231-140 - 246-231-140 - Advance notification of shipment of irradiated reactor fuel and nuclear waste. 0 (iv) for dangerous goods with a primary class of Class 1, Explosives, the compatibility group letter following the primary class. Have the answers at your fingertips. The three forms How to Ship Hazmat with No Packing Group | Lion Technology Some dangerous goods have multiple hazards. Subsidiary Classes Generally, a large means of containment must have four placards (one on each side, one on the front and one in back). The packing group may be preceded by the letters PG (for example, PG II); and. Mercury The solution or mixture is mentioned by name in the Dangerous Goods List; The name mentioned only applies to the pure substance; The hazard class or division, subsidiary risk, packing group or physical state of the mixture or solution is different from that of the substance mentioned; The hazard characteristics and properties of the mixture require different emergency response measures; Is it a pure substance or well-defined mixture (by use) or well-defined article? SAFETY DATA SHEET - Fisher Sci (iii) the primary class, which may be shown as a number only or under the heading Class or Classe or following the word Class or Classe. Wastes: If the product is a waste, then the shipping name is either preceded or followed by the word waste. TN Rules and Regs. WV Code Reg. Identification number - UN Number either within the center of the placard or on an orange panel safety mark (see the table for other safety marks) when required in Sections 4.15.2 of Part 4 in the TDG Regulation. If you use UN 3077 or UN 3082, the proper shipping name shall also be supplemented with technical names. Chemical family name (e.g., alcohol, ketone, etc. Self-heating solid, corrosive, organic, n.o.s. Code 5-481-3120 - 12VAC5-481-3120 - Advance notification of transport of nuclear waste. A proof of classification is a document that the consignor must provide, upon request, to the federal Minister of Transport. Also, regardless of the quantity of dangerous goods on board, the primary class placard for each of the dangerous goods in a large means of containment must be displayed on each side and on each end of the large means of containment or means of transport. Mercury Marine - Wikipedia class As Marine Pollutants Only: For a cylinder containing dangerous goods, the label must be displayed on or near the shoulder of the cylinder as shown below [Subsection 4.10(3)]. (iii) The following are excepted from the requirements of paragraph (a)(5) of this section: (A) Bulk packages, provided some indication of the total quantity is shown, for example, 1 cargo tank or 2 IBCs., (B) Cylinders, provided some indication of the total quantity is shown, for example, 10 cylinders.. hb```~ !o2)r10Dj`{0j@qz}]1%8Lt29+@b`t/c 9/fiF ~` C# If the dangerous goods are radioactive, the consignor must use the classification determined by the Canadian Nuclear Safety Commission. NOTE: See further belowin the table for placard requirement when the hazard class is 1.1, 1.2, 1.3, 1.4 or 1.5 are above a certain threshold of gross mass/number of articles. A placard is used for a large means of containment whose capacity is more than 450 L. The marks for safety for each TDG class are shown in the OSH Answers document Transportation of Dangerous Goods (TDG) - 9 Classes. Except for combustible liquids, the subsidiary hazard class(es) or subsidiary division number(s) must be entered in parentheses immediately following the primary hazard class or division number. Always checkwith Transport Canada andtheTDG Act and Regulationstoensure compliance. You need to ask yourself the following questions first and follow the above rules to determine accurate proper shipping names for your products. Have the answers at your fingertips. 61-63 - 61-63 - Radioactive Materials (Title A). The data below is an example showing UN1203, GASOLINE. Corrosives 9. The alphabetical order has been determined by ignoring all numerical digits and all lower case letters that precede the first capital letter in the shipping name. Peroxides. symbol (e.g., explosion, flames, corrosion, etc. Class 2.1 Dangerous Goods Image from Alberta EDGE (Environmental and Dangerous Goods Emergencies), Alberta Transportation. For the dangerous goods other than Class 1 DG, a Conveyance Permit (For Dangerous Goods other than Class 1 Dangerous Goods) is required. From the surface of Mercury, the Sun would appear more than three times as large as it does when viewed from Earth, and the sunlight would be as much as seven times brighter. Inorganic mercury compounds. Mercury is a metallic element released into the air as a vapour by natural processes and anthropogenic activities. Segregation if applicable, the classification method used under Part 2 of the TDG Regulations or under Chapter 2 of the UN Recommendations. <> Has a subsidiary classification of Class 1 (1.1,1.2, 1.3 above the exemption limits), Class 4.3, Class 6.1 (Packing Group I), Class 8 (applies only to UN numbers This mark is required when shipments meet the excepted quantity exemption. When test results and the hazard class criteria are compared, there are three possible conclusions: a) The laboratory test results show the product does not meet any of the criteria for the hazard classes. Regulatory information United States of America Inventory Component CAS-No TSCA TSCA Inventory notification - Active/Inactive TSCA - EPA Regulatory Flags Mercury Examples: COTTON WASTE, OILY (UN1364), or REGULATED MEDICAL WASTE, N.O.S. Note 4: As the dangerous good is not identified with UN3373, the Category B mark is not required. You may also find an expert in CSP business directory below. a document that explains how the dangerous goods were classified. Services Main Page. EDT. 33, Part XV, 1519 - 1519 - Advance Notification of Shipment of Irradiated Reactor Fuel and Nuclear Waste [Formerly 1516], 10 144 Me. See Column 4 in Schedule 1. ), 2. Please check if any of these measures apply to you. Although every effort is made to ensure the accuracy, currency and completeness of the information, CCOHS does not guarantee, warrant, represent or undertake that the information provided is correct, accurate or current. Are there any exemptions for placards? In this case, the product is not TDG regulated and the product does not need to comply with the TDG Regulations. This mark is displayed on small means of containment filled with infectious substances that are assigned to UN3373, Biological Substance Category B. Dangerous goods safety marks are the first line of communication about the hazard(s) of the dangerous good. 64-23-14 - 64-23-14 - Transportation of Radioactive Material. WebSubsidiary hazards must also be listed with the Basic Description. The requirements for the display of the dangerous goods safety marks also depend on: Labels and placards are diamond shaped (also referred to as square on point) and must be displayed as illustrated below. Column 3 Class or Division Contains the class and, in the case of class 1, the division and compatibility group. (b) Except as provided in this subpart, the basic description specified in paragraphs (a)(1), (2), (3), and (4) of this section must be shown in sequence with no additional information interspersed. When are dangerous goods safety marks required? I, II or III) assigned to the substance or article. This requirement is outlined in Part 5 of the TDG Regulations. For example: UN1993, FLAMMABLE LIQUID, N.O.S. Safety data sheet SECTION 1: Identification of the Solids containing flammable liquid, n.o.s. WebClass 1 Explosives; Class 2 Gases; Class 3 Flammable liquids; Class 4 Other Flammable Substances; Class 5 Oxidizing Substances & Organic Peroxides; Class 6 There are 4 types of entries consisting of UN numbers and proper shipping names in the Dangerous Goods List. NOTE: The table below is for guidance purposes only. Use the descriptive text written in lower case letters following a shipping name (see the example for UN1337 below) to determine the shipping name that most precisely describes the dangerous goods. Rules 007-001-RH-3509 - RH-3509 - Advance Notification of Shipment of Irradiated Reactor Fuel and Nuclear Waste. Make sure the appropriate labels (TDG or Workplace Hazardous Materials Information System (WHMIS) are used in the workplace as required. When the dangerous goods safety marks are, primary class label and each subsidiary class label for each of the dangerous goods, as well as the shipping name and UN number, must be displayed on the overpack, the word overpack is required on at least one side for overpacks with capacity less than 1.8 m3 (64 cubic feet), the words overpack on at least two opposite, required to display subsidiary hazard class placard. WebClassifying Substances That Are Included in More Than One Class or Packing Group The Primary class is shown first, with the subsidiary classes in brackets. Classification is defined in Part 1 of the TDG Regulations as: classification means, for dangerous goods, as applicable, the shipping name, the primary class, the compatibility group, the subsidiary class, the UN number, the packing group, and the infectious substance category.. p;k0;!N}?s7S&7! The Proper Shipping Name shall be supplemented with "MOLTEN"; Stabilized substances: Dangerous Goods of Class4.1, Packing Group II, not listed above, Magnesium or Magnesium alloys, with more than 50% magnesium, in pellets, turnings or ribbons, Naphthalene, crude or Naphthalene, refined, Titanium sponge granules or Titanium sponge powders, Dangerous Goods of Class4.1, Packing GroupIII, not listed above, Organometallic substance, solid, pyrophoric, water-reactive, Organometallic substance, liquid, pyrophoric, water-reactive, Phosphorus, white or Phosphorus, yellow, dry or Phosphorous, yellow, in solution or Phosphorous, yellow, underwater, Dangerous Goods of Class4.2, Packing Group I, not listed above, Potassium sulphide, anhydrous or Potassium sulphide, with less than 30% water of crystallization. What safety marks are required on a small means of containment (capacity 450L or less)? How do I determine the shipping name when there are several possible shipping names? Download the OSH Answers app for free. sponsor this page to leave your contact info on this page.. However, it would be prudent to hire a laboratory with appropriate accreditations. Substances (including substances and mixtures), and articles are assigned to one of the following 9 classes according to the most predominant hazards they pose in transport. The packing group for a dangerous good is determined by using the laboratory test data and comparing it to the criteria in Part 2. The symbol P used in this schedule means that the handling, offering for transport, and transporting of the dangerous goods by rail is prohibited. Mercury also combines with carbon to make organic mercury compounds. Determine the shipping name: Check if the product name is listed in Schedule 1 or Schedule 3. Special Provisions This column gives the special provisions that apply to the dangerous goods. Code tit. Founded in 1961 and headquartered in Los Angeles, Mercury has assets in excess of $4 billion, employs 4,500 people and has more than 8,000 independent agents in 11 states (Arizona, California, Regs. When shipping marine pollutants by sea, the proper shipping name shall be be supplemented with the technical name of the marine pollutant. They are substances that are identified as Marine pollutants in the IMDG Code Index or substances that satisfy the GHS classification criteria for Hazardous to Aquatic Environment Acute 1, Chronic 1, or Chronic 2. In response, we have issued some transportation-related measures and guidance. A substance, mixture, or article that is a marine pollutant and does not meet the classification criteria for inclusion in any other hazard class shall be declared under either UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, n.o.s. UN Dangerous Goods List Yes. China and Kyrgyzstan are the main producers of mercury. Mercury. (iii) For domestic shipments, primary and subsidiary hazard class or division names may be entered following the numerical hazard class or division, or following the basic description. If the product has already been classified, the consignor may use the TDG classification of the manufacturer or a previous consignor. WebListing, classification and packing Mercury (UN 2809): Subsidiary risk 6.1 Transmitted by the expert from Germany Introduction 1. The material's flash point will be displayed with the unit of measure and followed by "c.c." Indication of the packaging specification number (1H1) may be included in the description of the package (for example, 12 1H1 drums or 12 drums (UN 1A1)). Are there other requirements for labels on a small means of containment? WebIdentification Product Name Mercury (Certified ACS) Cat No. (vii) for dangerous goods that are subject to special provision 23, the words toxic by inhalation or toxic inhalation hazard or toxique par inhalation or toxicit par inhalation; Examples of classification descriptions of dangerous goods are: UN1214, ISOBUTYLAMINE, Class 3, Subsidiary Class (8), II, UN1214, ISOBUTYLAMINE, Class 3(8), Packing Group II, UN3381, TOXIC BY INHALATION LIQUID, N.O.S., Class 6.1 PG I, UN 1075 LIQUEFIED PETROLEUM GASES (propane); Not odourized, Class 2.1. More than one subsidiary class is possible. White asbestos (chrysotile, actinolite, anthophyllite, tremolite), Dangerous Goods of Class9, Packing Group III, Liquids, not listed above, Dangerous Goods of Class9, Packing GroupIII, Solids, not listed above. Mercury General Phosphorus sesquisulphide, free from yellow and white phosphorus, Rubber scrap or Rubber shoddy, powdered or granulated, not greater than 840 mm and rubber content greater than 45%. WebClassifying Substances That Are Included in More Than One Class or Packing Group. Ch. Figure 1: Label and placard (Image from Transport Canada). It can also negatively affect reproductive health. Consequently, the compatibility group will be already assigned by the Natural Resources Canada. What information is needed for classification? WebClass 3 material except PG I materials with a subsidiary hazard and UN1204, UN2059, UN3064, UN3256, UN3269 (unless authorized under SP A163), UN3357, UN3379, and UN3474 Division 4.1 PG II and PG III materials except UN2304, UN2448, UN2555, UN2556, UN2557, UN2907, UN3176, UN3221 through UN3240, UN3319 and UN3344 Select country for which that subsidiary belongs to.
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